S1 supporting information ch functionalization of benzothiazoles via thiazol2ylphosphonium intermediates you zi, fritz schomberg, konrad wagner and ivan vilotijevic. Ethyl ether in surface water will be subject to rapid volatilization with estimated halflives of 3. Diethyl ether is highly volatile and extremely flammable as a liquid or vapor. Diethyl ether cas no 60297 material safety data sheet sdsmsds. Page 4 of 8 msds t ethyl acetate reporting spills and releases to soil, water and air in excess of reportable quantities. Apr 27, 2015 previously used as an anesthetic, diethyl ether is an organic compound used primarily as a solvent. This gps safety summary s a highi level summary intended to provide the general public with an overview of product safety information on this chemical substance. Diethyl ether for gas chromatography ecd and fid suprasolv. Location open and dispense diethyl ether in a fume hood and store in appropriate area like inside a. See the hazard identif ication section for significant hazards. Safety data sheet northwest missouri state university.
Material safety data sheet diisopropyl ether extrapure section 1 chemical product and company identification msds name. Ethyl ether revision date 25apr2019 skin contact wash off immediately with plenty of water for at least 15 minutes. Safety data sheet ethyl ether bdh1121 page 8 15 version 1. Diethyl ether, acs reagent, anhydrous, acros organics. The toll free number for the us coast guard national response center is 800 4248802. Under the 2005 guidelines for carcinogen risk assessment u. Symptoms include itching, burning, redness and tearing. Material safety data sheet safety data sheet diethyl ether section 1. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Gps safety summary diethyl ether 17 august 2015 page 1 of 5 global product strategy gps safety summary. California prop 65 california no significant risk level. Page 1 of 2 diethyl ether university of michiganflint. Smartlab indonesia msds diethyl ether page 2 material safety data sheet diethyl ether revision. It is considered one of the most dangerous fire hazards commonly used in the lab due to its volatility and extremely low ignition temperature.
Diethyl ether material safety data sheet cas no 60297 sdsmsds. Find msds or sds, a coa, data sheets and more information. Chemical product and company identification product name. Material safety data sheet petroleum ether msds number. If ethyl ether is released to the atmosphere, it will be expected to exist almost entirely in the vapor phase. The substance identity section is calculated from substance identification information from all echa databases. Diethyl ether safety data sheet according to federal register vol. Ch functionalization of benzothiazoles via thiazol2yl. An ether may be a product of the condensation of alcohols. Methly tertbutyl ether breathing, give artificial respiration. Ghs classification in accordance with 29 cfr 1910 osha hcs. Identification of the substancepreparation and of the companyundertaking. Global product strategy gps safety summary diethyl ether.
Symptoms of such overexposure to dimethyl ether can produce anesthetic effects sleepiness, loss of coordination, fatigue, as well as headaches, dizziness, nausea, and unconsciousness. Thermo fisher scientific ethyl ether revision date 26sep2009 t indicates a substance that is the subject of a section 4 test rule under tsca. Material safety data sheet diisopropyl ether extrapure. If medical advice is needed, have product container or. If the pdf does not display below, you may also download it here. Ether also refers loosely to diethyl ether, a colorless, volatile, highly inflammable liquid used in industry and biomedical research, and historically important as an anesthetic agent. Dscl eec all ingredients are listed on the dscl inventory. Diethyl ether revision 1 revision date 0804 2015 16. If medical advice is needed, have product container or label at hand.
If seeking medical attention provide sds document to physician. Material safety data sheetmsds ethyl acetate synonyms. It is commonly used as a solvent in laboratories and as a starting fluid for some engines. Pictogram signal word danger hazard statements h224 extremely flammable liquid and vapour. Material safety data sheet msds hydrochloric acid product name. Physical and chemical properties molecular formula ch 3 ch 2 2 o. Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Understanding the safety risks of diethyl ether msdsonline. The most significant hazard associated with dimethyl ether is inhalation of vapors. Derivation of quantitative estimates of cancer risk for diethyl ether is precluded. If the pdf does not display below, you may also download it. Supplemental hazard statements euh019 may form explosive peroxides. Do not use mouthtomouth method if victim ingested or inhaled the substance.
However, we make no warranty of merchantability or any other warranty. If ethyl ether is released to the atmosphere, it will be expected to exist almost entirely in the. Firstaid measures eyes rinse with plenty of water for at least 15 minutes and seek medical attention immediately. Diethyl ether cas 60297 for analysis emsure acs,iso,reag. Petroleum ether is classified by acgih as class 3, confirmed animal carcinogen with unknown relevance to humans. Severe inhalation exposure can be fatal, due to dimethyl ether. Inhalation move casualty to fresh air and keep at rest. Regulatory information tsca inventory status all ingredients are listed on the tsca inventory. In case of skin contact take off contaminated clothing and shoes immediately.
Sigmaaldrich offers a number of dimethyl ether products. Due to its extreme flammability and other potential hazards, diethyl ether should be stored and handled with extreme care in the workplace. Diethyl ether cas no 60297 material safety data sheet. Diethyl ether will spontaneously ignite at temperatures at or above 160c 320f. Safety data sheet ghs product identifier other means of. Acgih threshold limit values diethyl ether 60297 pel. This protocol leads to the cc bond formation of tertiary and quaternary stereogenic centers with high enantioselectivity. Diethyl ether is commonly used as a solvent and for liquidliquid extraction. Diethyl ether, or simply ether, is an organic compound in the ether class with the formula c 2 h 5 2 o, sometimes abbreviated as et 2 o see pseudoelement symbols.
Product and company identification ethyl ether synonymsgeneral names. Ether is an organic compound in which two carbon atoms are linked through an oxygen atom coc. Smartlab indonesia msds diethyl ether page 3 material safety data sheet diethyl ether revision. Epa, 2005, inadequate information is available to assess the carcinogenic potential of diethyl ether. If a leak or spill has not ignited, use water spray to disperse the vapors, to prote ct personnel attempting to stop leak. Chemical product identifier and synonyms product name. This colorless, highly volatile chemical has a pungent, yet somewhat sweet odor. Safety data sheet according to 29cfr19101200 and ghs rev. Material safety data sheet diethyl ether msds finar limited. Liquid fire starting fluid m3911c msds revision date. Material safety data sheet skunk pharm research llc.
This material is not known or reported to be carcinogenic by any reference source including iarc, osha, ntp, or epa. Section 1 chemical product and company identification. Ph eur find msds or sds, a coa, data sheets and more information. Our msds database is an easy to use, do it yourself tool, and best of all. Ethylene glycol monomethyl ether certified revision date 17jan2018 may cause damage to organs through prolonged or repeated exposure precautionary statements prevention obtain special instructions before use do not handle until all safety precautions have been read and understood use personal protective equipment as required. Xu indicates a substance exempt from reporting under the inventory update rule, i. Material safety data sheet diethyl ether msds section 1.
State diethyl ether d10 is not present on state lists from ca, pa, mn, ma, fl, or nj. Diethyl ether material safety data sheet cas no 6029. Ethyl ether will not significantly photooxidize via reaction with photochemically produced hydroxyl radicals in the water. It was formerly used as a general anesthetic, until nonflammable drugs were developed.
Skin contact wash off immediately with plenty of water for at least 15 minutes. H224, h302, h336 ether, anhydrous, acs created by global safety management, 184355161. Identification of the substancemixture and of the companyundertaking. Msds contains all of the information required by those regulations. Dispose of contents and container in accordance with all local, regional, national and. It will not be expected to hydrolyze in water or soil. Show this safety data sheet to the doctor in attendance. If inhaled if breathed in, move person into fresh air. Chemical product and company identification flammable gas mixture. Dimethyl ether 115106 dimethyl ether safety data sheet p4589 this sds conforms to u. Due to product restrictions, please sign in to purchase or view availability for this product. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Material safety data sheet diethyl phthalate msds section 1. Mek downwind areas if required due to toxicity or flammability of th e material.
The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the. Canadian ingredient disclosure list section 16 additional information msds creation date. Diethyl ether material safety data sheet cas no 60297. No data availablebis2ethoxyethyl ether specific target organ toxicity repeated exposure no data available aspiration hazard no data availablebis2ethoxyethyl ether additional information rtecs. It is a colorless, highly volatile flammable liquid.
In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Repeated or extended contact may cause erythema reddening of the skin or dermatitis, resulting from a defatting action on tissue. Diethyl ether is highly flammable and must be kept away from heatsparksopen flameshot surfaces. Ethylene glycol monomethyl ether certified revision date 17jan2018 eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Overexposure to dimethyl ether may cause the following health effects.